I'm processing pure Ni and Ni-based coatings für catalysis meanings (porous coatings with primray particle sizes of about 10 nm) in a plasma process. The problem is, that the samples are handled in air after the coating process, meaning that the coating layers a prone to oxidation. I'm currently searching a way to prevent this (for catalysis meanings detrimentral) surface oxidation. Maybe there is a possibility to treat the surface in-situ (meaning before venting the plasma vacuum chamber) with a passivation gas.
My question to you is: Is there any known gas that passivates the catalytic surface without having a deleterious effect on catalytic activity?
Any answer with helpful hints or publications would be very appreciated.